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Phosphoric Acid → Zinc Phosphate

HRID 353680
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HRID 353680 반응식
C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2:21].C([O-])(=O)CCCCCCCCCCCCCCCCC.[P:42](=[O:46])([OH:45])([OH:44])[OH:43].C([O:65][P:66](=[O:69])([OH:68])[OH:67])CCCCCCCCCCCCCCCCC.C(OP(=O)(O)OCCCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCC.[Zn].O=P12OP3(OP(OP(O3)(O1)=O)(=O)O2)=O>[Fe]>[P:42]([O-:46])([O-:45])([O-:44])=[O:43].[Zn+2:21].[P:66]([O-:69])([O-:68])([O-:67])=[O:65].[Zn+2:21].[Zn+2:21]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

8

반응물 6

HCID 1004Phosphoric AcidHCID 11178Zinc StearateHCID 14812Phosphorus oxide (P4O10)HCID 23994ZincHCID 76290Monostearyl phosphateHCID 76433Distearyl phosphate

생성물 1

HCID 24519
Zinc Phosphate

시약·촉매·용매 1

HCID 23925Iron촉매2회

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온도
550 °C

실험 절차

A mixture of iron powder and zinc stearate and a mono, di or triester of phosphoric acid and long-chain alcohols, such as a mixture of phosphoric acid monostearyl ester and phosphoric acid distearyl ester having a melting point of 70° C., as antitack agent was pressed to form a molded article, the proportion of the antitack agents with respect to the weight of the iron powder being approximately 1.7% by weight, and the atomic ratio Zn:P being approximately 3:2. The molded article was heated in a nonreducing atmosphere, such as in nitrogen, to a maximum temperature of approximately 550° C., the antitack agents pyrolyzing to ZnO and P2O5, and the oxides reacting with each other to form zinc phosphate. As was determined, zinc phosphate has a high specific electrical resistance, adheres well to metals and protects especially iron from corrosion. The composite material obtained is suitable as a soft magnetic material for fast-acting electric valves.

후처리

  1. customto form a molded article

출처 및 근거

ORD 기록
ord-d870619da2c040549891ceda196db4df
출처 데이터셋
uspto-grants-2004_06
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06756118B2

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