1,4-Dichlorobenzene → 3,4'-Dichlorodiphenyl ether

반응식

[OH-].[Na+].[Cl:3][C:4]1[CH:5]=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1.[Cl:11][C:12]1[CH:17]=[CH:16][C:15](Cl)=[CH:14][CH:13]=1.CC(N(C)C)=O>>[CH:8]1[CH:9]=[C:4]([Cl:3])[CH:5]=[C:6]([O:10][C:15]2[CH:16]=[CH:17][C:12]([Cl:11])=[CH:13][CH:14]=2)[CH:7]=1

참가 물질

반응물 4

HCID 46851,4-Dichlorobenzene

HCID 79333-Chlorophenol

HCID 14798Sodium Hydroxide

HCID 31374Dimethylacetamide

생성물 1

HCID 812833,4'-Dichlorodiphenyl ether

실험 절차

80 g (1 mol) of 50% sodium hydroxide are added to a solution of 128.1 g (1 mol) of 3-chlorophenol in 1325 g (9 mol) of 1,4-dichlorobenzene and 27 g (0.3 mol) of dimethylacetamide.

출처 및 근거

ORD 기록: ord-dca331bd7c724979a783dd4f38301cb2
출처 데이터셋: uspto-grants-1988_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04766253

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