Gluconic Acid → D-Arabitol

HRID 355499

반응식

HRID 355499 반응식
[O:1]=[CH:2][C@H:3]([C@@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].O=C(O)[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O>>[CH2:2]([OH:1])[C@H:3]([C@@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4]

참가 물질

4

반응물 3

HCID 10690Gluconic AcidHCID 66308D-ArabinoseHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 94154D-Arabitol

실험 절차

An alternative synthesis of D-arabinose consists in the oxidative degradation of gluconic acid, extensively described by Ruff in Berichte der Deutschen Chemischen Gesellschaft 32 (1899) 553-554. However, starting from glucose a minimum of three reaction steps are required to obtain arabinitol.

후처리

  1. customa minimum of three reaction steps

출처 및 근거

ORD 기록
ord-aa35eb104675409f9f0f65b0231ecdc1
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05831078

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