Phthalonitrile → Gallium phthalocyanine

HRID 355619

반응식

HRID 355619 반응식
[C:1](#[N:10])[C:2]1[C:3](=[CH:6][CH:7]=[CH:8][CH:9]=1)[C:4]#[N:5].C[O-].C[O-].C[O-].[Ga+3:17]>C(O)CO>[Ga:17].[CH:7]1[CH:8]=[CH:9][C:2]2[C:3](=[C:4]3[N:5]=[C:4]4[N:10]=[C:1]([C:2]5[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=54)[N:10]=[C:1]4[NH:5][C:4]([C:3]5[CH:6]=[CH:7][CH:8]=[CH:9][C:2]=54)=[N:10][C:1]4=[N:5][C:4]([C:3]5[CH:6]=[CH:7][CH:8]=[CH:9][C:2]=54)=[N:10][C:1]=2[NH:5]3)[CH:6]=1

참가 물질

4

반응물 2

HCID 7042PhthalonitrileHCID 131719385HCID 131719385, 화합물

생성물 1

HCID 136138306Gallium phthalocyanine

시약·촉매·용매 1

HCID 174Ethylene Glycol용매

반응 조건

온도
200 °C

실험 절차

A mixture of 29.1 parts of phthalonitrile, 9.2 parts of gallium trimethoxide, and 150 parts of ethylene glycol was stirred for 24 hours at 200° C. in a nitrogen atmosphere, and the product was filtered. The product was successively washed with N,N-dimethylformamide and then methanol, and dried to provide 23.0 parts of gallium phthalocyanine.

후처리

  1. filtrationthe product was filtered
  2. washThe product was successively washed with N,N-dimethylformamide
  3. dry with materialmethanol, and dried

출처 및 근거

ORD 기록
ord-6a845a6c48a24eedaa0d7c9939fef0a4
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05834149

연결된 노트

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