Dimethylformamide → Benzaldehyde, 4-(diphenylamino)-

HRID 357466

반응식

HRID 357466 반응식
[C:1]1([N:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CN([CH:23]=[O:24])C.P(Cl)(Cl)(Cl)=O>O>[C:14]1([N:7]([C:1]2[CH:2]=[CH:3][C:4]([CH:23]=[O:24])=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

참가 물질

5

반응물 3

HCID 6228DimethylformamideHCID 11775TriphenylamineHCID 24813Phosphorus oxychloride

생성물 1

HCID 77846Benzaldehyde, 4-(diphenylamino)-

시약·촉매·용매 1

HCID 962Water용매

실험 절차

101.4 g of triphenylamine and 35.5 mL of DMF were placed in a three-neck flask, and while stirring with cooling in ice water, 84.4 mL of phosphorus oxychloride was dripped into the flask; the reaction mixture was hold at 95° C. for 5 hours. It was poured into 4 L of hot water and stirred for 1 hour. The precipitate was then collected and washed with a 1:1 mixture of ethanol/water, and 4-(N, N-diphenylamino) benzaldehyde was obtained. The yield was 91.5 g (81.0%).

후처리

  1. customat 95° C.
  2. customfor 5 hours
  3. stirringstirred for 1 hour
  4. customThe precipitate was then collected
  5. washwashed with a 1:1 mixture of ethanol/water

출처 및 근거

ORD 기록
ord-d4a47c6745094e319cc6050d0f4f6f96
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05840816

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