홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Epichlorohydrin → Isostearyl glycidyl ether

HRID 358312
노트
인쇄 미리보기

반응식

HRID 358312 반응식
[OH-].[Na+].[CH2:3]([OH:21])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH:18]([CH3:20])[CH3:19].[CH2:22]([CH:24]1[O:26][CH2:25]1)Cl>[Cl-].C([N+](C)(C)C)CCCCCCCCCCCCCCCCC.CCCCCC>[CH2:22]([O:21][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH:18]([CH3:19])[CH3:20])[CH:24]1[O:26][CH2:25]1
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 3

HCID 7835Epichlorohydrin2회HCID 14798Sodium HydroxideHCID 62825Isostearyl Alcohol EX

생성물 1

HCID 22622804Isostearyl glycidyl ether수율 83.2%

시약·촉매·용매 2

HCID 8155Stearyltrimethylammonium chloride촉매HCID 8058Hexane
용매

반응 조건

온도
50 °C

실험 절차

Into a round bottom flask having a capacity of 1 liter and equipped with a reflux condenser, a thermometer, a dropping funnel, and a stirring means, 120 g of a 50% sodium hydroxide solution (60 g (1.5 mole) as pure sodium hydroxide), 68 g (0.25 mole) of isostearyl alcohol [5,7,7-trimethyl-2-(1,3,3-trimethylbutyl) octanol], 200 ml of n-hexane, and 2.51 g (0.0075 mole) of stearyl trimethyl ammonium chloride, were introduced in this order. The reaction mixture was kept at a reaction temperature of 25° C. in a water bath, and while vigorously stirring the mixture at a stirring speed of 400 r.p.m., 93 g (1 mole) of epichlorohydrin was added dropwise from the dropping funnel. It took about 1.5 hours for the addition of the epichlorohydrin, and the reaction mixture was heated to 50° C. and stirred for about 8 hours at this temperature. After the completion of the reaction, the mixture was treated in a usual manner, whereupon 67.9 g (yield: 83%) of isostearyl glycidyl ether (5,7,7-trimethyl-2-(1,3,3-trimethylbutyl)-octyl glycidyl ether) was obtained.

후처리

  1. customInto a round bottom flask having
  2. customa capacity of 1 liter and equipped with a reflux condenser
  3. customThe reaction mixture was kept at a reaction temperature of 25° C. in a water bath
  4. customAfter the completion of the reaction

출처 및 근거

ORD 기록
ord-f627163b3e1b4da8aeca592dd6510e85
출처 데이터셋
uspto-grants-1984_08
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04465869

반응 노트

불러오는 중…

이 페이지에서참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트