Picryl Chloride → 2,4,6-Trinitrophenylacetic acid

HRID 358858

반응식

HRID 358858 반응식
Cl[C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5]([N+:11]([O-:13])=[O:12])=[CH:4][C:3]=1[N+:14]([O-:16])=[O:15].C(OCC)(=O)[CH2:18][C:19]([O-:21])=[O:20].[Na]>>[N+:14]([C:3]1[CH:4]=[C:5]([N+:11]([O-:13])=[O:12])[CH:6]=[C:7]([N+:8]([O-:10])=[O:9])[C:2]=1[CH2:18][C:19]([OH:21])=[O:20])([O-:16])=[O:15]

참가 물질

4

반응물 3

HCID 6953Picryl ChlorideHCID 3595298Propanedioic acid, monoethyl esterHCID 5360545Sodium

생성물 1

HCID 3294642,4,6-Trinitrophenylacetic acid

실험 절차

2,4,6-Trinitrophenylacetic acid (mp 159°-160° C.) is prepared from 1-chloro-2,4,6-trinitrobenzene and ethyl malonate in the presence of metallio sodium in accordance with a procedure by M. Kimura in J. Pharm. Soc. Jpn., 73, 1216 (1953).

출처 및 근거

ORD 기록
ord-1bfa364d9d334dda99662b3f56fb0083
출처 데이터셋
uspto-grants-1991_03
특허 번호
US04997977

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