Antioxidant 1010 → Allyl methacrylate

HRID 359339

반응식

HRID 359339 반응식
[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH3:7][CH2:8][CH2:9]C[N+](CCCC)(CCCC)CCCC.[F-].CC(C1C(O)=C(C(C)(C)C)C=C(CCC(OCC(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)=O)C=1)(C)C>C1COCC1>[C:1]([O:6][CH2:9][CH:8]=[CH2:7])(=[O:5])[C:2]([CH3:4])=[CH2:3]

참가 물질

5

반응물 3

HCID 64819Antioxidant 1010HCID 87595MethacrylateHCID 2724141Tetrabutylammonium Fluoride

생성물 1

HCID 7274Allyl methacrylate

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

To a stirred solution of MTS (5.5 x 10-3 g) in dry THF (10.0 ml) was added (D2.1) (3.0 g), AM (0.11 ml) and TBAF (2 μl of 1M THF solution). The mixture warmed up and was stirred overnight at room temperature. 50 ppm Irganox 1010 antioxidant was added to the very viscous clear solution, which was cast into a polyester tray in a stream of nitrogen. The last traces of THF were removed by heating in a vacuum oven at 60° for 4 hours.

후처리

  1. temperatureThe mixture warmed up
  2. customThe last traces of THF were removed
  3. temperatureby heating in a vacuum oven at 60° for 4 hours

출처 및 근거

ORD 기록
ord-bad2879baff8427fb1dea59486c1f0ab
출처 데이터셋
uspto-grants-1991_03
특허 번호
US05001023

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