Acetyl chloride → HCID 137226513, 화합물

HRID 35962

반응식

HRID 35962 반응식
[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5].[C:9](Cl)(=[O:11])[CH3:10].C(N(CC)CC)C>ClC(Cl)C>[C:9]([OH:11])(=[O:5])[CH3:10].[C:9]([OH:11])(=[O:5])[CH3:10].[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5]

참가 물질

5

반응물 3

HCID 6367Acetyl chlorideHCID 8471TriethylamineHCID 135527345Ethanediimidoyl dichloride, dihydroxy-

생성물 1

HCID 137226513HCID 137226513, 화합물수율 30%

시약·촉매·용매 1

HCID 63651,1-Dichloroethane용매

실험 절차

The mixture of 2.0 g (0.0127 mol) of dichloroglyoxime (Compound No.6), 20 ml of dichloroethane and 2.4 g (0.0306 mol) of acetyl chloride was stirred in an ice bath. To the mixture, triethylamine (3.1 g, 0.0307 mol) was added dropwise, followed by stirring for 30 minutes. The reaction mixture was washed twice with 15 ml of water. The dichloroethane solution was concentrated under reduced pressure, to obtain white crystals of dichloroglyoxime diacetate (Compound No.2, yield: 30%).

후처리

  1. stirringby stirring for 30 minutes
  2. washThe reaction mixture was washed twice with 15 ml of water
  3. concentrationThe dichloroethane solution was concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-8cf7e900532942bd97b5cb69fa438ac1
출처 데이터셋
uspto-grants-1995_05
특허 번호
US05411990

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