Methyl 3-allyl-4-hydroxybenzoate → Methyl 4-hydroxy-3-propylbenzoate

HRID 363038

반응식

HRID 363038 반응식
[OH:1][C:2]1[CH:11]=[CH:10][C:5]([C:6]([O:8][CH3:9])=[O:7])=[CH:4][C:3]=1[CH2:12][CH:13]=[CH2:14]>CCOC(C)=O.[Pd]>[OH:1][C:2]1[CH:11]=[CH:10][C:5]([C:6]([O:8][CH3:9])=[O:7])=[CH:4][C:3]=1[CH2:12][CH2:13][CH3:14]

참가 물질

4

반응물 1

HCID 939882Methyl 3-allyl-4-hydroxybenzoate

생성물 1

HCID 11805593Methyl 4-hydroxy-3-propylbenzoate

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8857Ethyl Acetate용매

실험 절차

To 22-3 (6.0 g, 33.2 mmol) in 50 mL of EtOAc was added 60 mg of 5% Pd on carbon and the whole was hydrogenated at atmospheric pressure for 24 h. Hydrogen was removed from the reaction mixture and the solution was filtered through Celite. Evaporation of the solvent afforded product 22-4 as a white solid.

후처리

  1. customHydrogen was removed from the reaction mixture
  2. filtrationthe solution was filtered through Celite
  3. customEvaporation of the solvent

출처 및 근거

ORD 기록
ord-f01451e0f3f640d8932c8f76d798ecf0
출처 데이터셋
uspto-grants-1999_02
특허 번호
US05872138

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