p-n-Octadecyloxybenzoic acid → 4-(trans-3-Decenyloxy)-benzoic acid

HRID 369538

반응식

HRID 369538 반응식
C[O:2][C:3](=[O:21])[C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH:6][CH:5]=1.O.[OH-].[Li+].C(OC1C=CC(C(O)=O)=CC=1)CCCCCCCCCCCCCCCCC>CO>[CH2:11]([O:10][C:7]1[CH:6]=[CH:5][C:4]([C:3]([OH:21])=[O:2])=[CH:9][CH:8]=1)[CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

참가 물질

5

반응물 3

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrateHCID 18521096Methyl-4-(trans-3-decenyloxy)-benzoate

생성물 1

HCID 185211034-(trans-3-Decenyloxy)-benzoic acid

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

Ester 35h (600 mg, 2.07 mmol), and lithium hydroxide monohydrate (867 mg, 20.7 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 500 mg (87%) of a white powder which was not quite pure (95%). The product was used without further purification.

후처리

  1. customThe product was used without further purification

출처 및 근거

ORD 기록
ord-b213ca41cefd427f9bb23e37e0e5988d
출처 데이터셋
uspto-grants-2000_10
특허 번호
US06139771

연결된 노트

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