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Ethanolamine → ethyl N-(2-hydroxyethyl)carbamate

HRID 36959
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HRID 36959 반응식
[CH2:1]([CH2:3][NH2:4])[OH:2].[C:5]1(=O)[O:9][CH2:8][CH2:7][O:6]1>C(O)C>[OH:2][CH2:1][CH2:3][NH:4][C:5]([O:6][CH2:7][CH3:8])=[O:9]
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참가 물질

4

반응물 2

HCID 700EthanolamineHCID 7303Ethylene carbonate

생성물 1

HCID 223805ethyl N-(2-hydroxyethyl)carbamate

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

40.6 grams of ethanolamine were charged to a standard neck reaction vessel fitted with an agitator, packed column and a thermometer. 70.3 grams of ethylene carbonate was added, and the temperature was allowed to rise to 100° C. The mixture was then held at 100° C. for 2 hours. The crude 2-hydroxyethyl urethane of ethanol formed had a viscosity of 4.5 poise at 30° C. (as measured by an ICI cone and plate viscometer) and a base number of 3.0. The residual base number corresponded to a conversion of amine to urethane of 99.4%. The mixture was heated to 150° C. and 689.1 grams of dodecanedioic acid were added. The solution was heated slowly to 220° C., with water being removed continuously, over a 1.5 hour period. The reaction product was then cooled and poured out. The final product had a melting point of 81° C. to 84° C.

후처리

  1. customfitted with an agitator
  2. customto rise to 100° C

출처 및 근거

ORD 기록
ord-b8a85cdd07a64da388d31047bc6750c6
출처 데이터셋
uspto-grants-1995_05
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05418292

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