Acetic Anhydride → HCID 12803438, 화합물

반응식

[CH3:1][O:2][CH2:3][CH2:4][N:5]1[CH:9]=[C:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[NH:7][C:6]1=[O:16].[C:17](OC(=O)C)(=[O:19])[CH3:18]>>[CH3:1][O:2][CH2:3][CH2:4][N:5]1[CH:9]=[C:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[N:7]([C:17](=[O:19])[CH3:18])[C:6]1=[O:16]

참가 물질

반응물 2

HCID 7918Acetic Anhydride

HCID 12803422HCID 12803422, 화합물

생성물 1

HCID 12803438HCID 12803438, 화합물

실험 절차

Approximately 21.8 g of 1-(2-methoxyethyl)-4-phenyl-4-imidazolin-2-one and 120 ml. of acetic anhydride is refluxed together for four hours. The acetic anhydride is distilled out at reduced pressure. The residual semisolid is recrystallized from ether to yield the title compound as a white solid; m.p. 73°-75° C.

후처리

distillationThe acetic anhydride is distilled out at reduced pressure
customThe residual semisolid is recrystallized from ether

출처 및 근거

ORD 기록: ord-a50e3baf93f1486888ba1bdab52b26b4
출처 데이터셋: uspto-grants-1978_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04087611

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