4-(4-Octyloxyphenyl)benzoyl chloride → 4-(2-Pentanoyloxy-1-keto-propyl)-phenyl 4'-octyloxybiphenyl-4-ylcarboxylate

HRID 373463노트

반응식

HRID 373463 반응식
[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22](Cl)=[O:23])=[CH:18][CH:17]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(C1C=CC(C2C=CC(C(OC(C)C(C3C=CC(OCC=C)=CC=3)=O)=O)=CC=2)=CC=1)CCCCCC.[C:61]([O:67][CH:68]([CH3:78])[C:69]([C:71]1[CH:76]=[CH:75][C:74]([OH:77])=[CH:73][CH:72]=1)=[O:70])(=[O:66])[CH2:62][CH2:63][CH2:64][CH3:65]>CN(C1C=CN=CC=1)C>[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22]([O:77][C:74]3[CH:75]=[CH:76][C:71]([C:69](=[O:70])[CH:68]([O:67][C:61](=[O:66])[CH2:62][CH2:63][CH2:64][CH3:65])[CH3:78])=[CH:72][CH:73]=3)=[O:23])=[CH:18][CH:17]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

5

반응물 3

HCID 110784734-(4-Octyloxyphenyl)benzoyl chlorideHCID 198100571-Methyl-2-(4'-allyloxy-phenyl)-2-keto-ethyl 4'-heptylbiphenyl-4-ylcarboxylateHCID 198101294-(2-Pentanoyloxy-1-keto-propyl)phenol

생성물 1

HCID 198100404-(2-Pentanoyloxy-1-keto-propyl)-phenyl 4'-octyloxybiphenyl-4-ylcarboxylate

시약·촉매·용매 1

HCID 142844-(Dimethylamino)pyridine촉매

실험 절차

A mixture of 500 mg of 4'-octyloxy-biphenyl-4-yl-carboxylic acid chloride, 400 mg of (S) 4-(2-pentanoyloxy-1-keto-propyl)phenol, 600 mg of N,N-dicyclohexylcarbodiimide, and 20 mg of DMAP was stirred at room temperature for three hours. A solid material precipitated was removed by filtration. The organic layer thus obtained was washed with an acid, an alkali, and with water, dried, and then concentrated.

후처리

  1. customA solid material precipitated
  2. customwas removed by filtration
  3. customThe organic layer thus obtained
  4. washwas washed with an acid
  5. dry with materialan alkali, and with water, dried
  6. concentrationconcentrated

출처 및 근거

ORD 기록
ord-af6d64d2a7ba4b25a4acd3588fc4cde5
출처 데이터셋
uspto-grants-1992_11
특허 번호
US05164112

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