Toluene → 1-Ethyl-4-Methylbenzene

HRID 374724

반응식

HRID 374724 반응식
[N+]([O-])([O-])=O.[Ca+2].[N+]([O-])([O-])=O.[C:10]1([CH3:16])[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[CH3:17][C:18]1[CH:19]=[CH:20][C:21]([CH3:24])=[CH:22][CH:23]=1>ClCCl>[CH2:16]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH3:17].[CH2:17]([C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1)[CH3:10]

참가 물질

6

반응물 3

HCID 1140TolueneHCID 7809P-XyleneHCID 24963Calcium nitrate

생성물 2

HCID 7500Ethylbenzene수율 86%HCID 121601-Ethyl-4-Methylbenzene수율 89%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Pilot-scale treatments also support the laboratory incubations. The addition of calcium nitrate to the sediments of the Dofasco Boatslip in 1992 resulted in the biodegradation of several organic compounds (mean of three samples, reductions as follows; toluene 80%, ethylbenzene 86%, m/p-xylene 76%, 3/4-ethyltoluene 89%, and dichloromethane 65%) (FIG. 29). These relatively rapid biodegradation rates are similar to those reported in laboratory studies where nitrate was added to enhance biodegradation (Hutchins 1991).

출처 및 근거

ORD 기록
ord-815d51115fc74d2f826bc2eee2c15095
출처 데이터셋
uspto-grants-1996_01
특허 번호
US05481815

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