1,2-Dimethoxyethane → Triphenylstannane

HRID 376828

반응식

HRID 376828 반응식
[BH4-].[Na+].C(COC)OC.[C:9]1([Sn:15](Cl)([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>COCCOCCOC>[C:22]1([SnH:15]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

참가 물질

5

반응물 3

HCID 80711,2-DimethoxyethaneHCID 12540Triphenyltin ChlorideHCID 4311764Sodium borohydride

생성물 1

HCID 6460Triphenylstannane수율 100%

시약·촉매·용매 1

HCID 8150Diglyme용매

반응 조건

온도
-10 °C

실험 절차

3.9 g of sodium borohydride (0.1 mol) and 70 ml of monoglyme were mixed together in a 200 ml eggplant type flask and cooled to -10° C. 70 ml of a diglyme solution containing 10.0 g of triphenyltin chloride (0.026 mol) was added to this mixture dropwise for 30 minutes. Subsequently, the mixture was stirred for another 30 minutes at -10° C. Then diglyme was removed under a reduced pressure of greater than 1 mmHg at below 0° C. Then, the resultant residue was extracted with diethylether followed by concentration under reduced pressure to yield 9.1 g of the final product of triphenyltin hydride (yield=100%).

후처리

  1. additionwas added to this mixture dropwise for 30 minutes
  2. customThen diglyme was removed under a reduced pressure of greater than 1 mmHg at below 0° C
  3. extractionThen, the resultant residue was extracted with diethylether
  4. concentrationfollowed by concentration under reduced pressure

출처 및 근거

ORD 기록
ord-c7b4f3644fb94eda8ba0b0c4d70f7677
출처 데이터셋
uspto-grants-2000_02
특허 번호
US06022822

연결된 노트

불러오는 중…