3-Butenylbenzene → 2-(2-Phenylethyl)oxirane

HRID 376925

반응식

HRID 376925 반응식
ClC1C=CC=C(C(OO)=[O:9])C=1.[C:12]1([CH2:18][CH2:19][CH:20]=[CH2:21])[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>C(Cl)(Cl)Cl>[O:9]1[CH2:21][CH:20]1[CH2:19][CH2:18][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

참가 물질

4

반응물 2

HCID 130333-ButenylbenzeneHCID 70297m-Chloroperbenzoic acid

생성물 1

HCID 1359552-(2-Phenylethyl)oxirane수율 100%

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

A solution of m-chloroperbenzoic acid (43.5 g, 151 mmol) in chloroform (250 ml) was treated with 4-phenyl-1-butene (20 g, 151 mmol). The reaction was stirred for 1 hour at room temperature and washed with sodium bicarbonate, sodium sulfite, and saturated sodium chloride. The solution was dried over sodium sulfate and evaporated to dryness to afford 3,4-epoxybutylbenzene (100%).

후처리

  1. washwashed with sodium bicarbonate, sodium sulfite, and saturated sodium chloride
  2. dry with materialThe solution was dried over sodium sulfate
  3. customevaporated to dryness

출처 및 근거

ORD 기록
ord-3d23a47006cb467d9e7541d480e9a115
출처 데이터셋
uspto-grants-2000_02
특허 번호
US06022894

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