2-Methylbenzyl alcohol → 2-Methylbenzaldehyde

HRID 379362

반응식

HRID 379362 반응식
CC1C=CC=CC=1C.N[C:10]1[CH:21]=[CH:20][CH:19]=[C:12]2[C:13](N(O)[C:16](=O)[C:11]=12)=[O:14].CC1C=CC=CC=1CO>>[CH3:16][C:11]1[CH:10]=[CH:21][CH:20]=[CH:19][C:12]=1[CH:13]=[O:14]

참가 물질

4

반응물 3

HCID 69942-Methylbenzyl alcoholHCID 7237O-XyleneHCID 108884723-amino-N-hydroxyphthalimide2회

생성물 1

HCID 107222-Methylbenzaldehyde수율 30%

실험 절차

170 mg (1.60 mmol) of o-xylene were reacted analogously to Example 1 in the presence of 32.1 mg (0.180 mmol) of 3-amino-N-hydroxyphthalimide. After a reaction time of 4 hours and 18 hours, a further 32.1 mg (0.180 mmol) of 3-amino-N-hydroxyphthalimide were added in each case, and, after a total of 30 hours, the reaction solution was extracted with chloroform and examined by NMR spectroscopy. Yield 30% of 2-methylbenzaldehyde and 7% of 2-methylbenzyl alcohol.

후처리

  1. extractionafter a total of 30 hours, the reaction solution was extracted with chloroform

출처 및 근거

ORD 기록
ord-1891e06b840d49d48dfd203a556d703d
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06297403B1

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