1-Propanethiol, 3-(triethoxysilyl)- → Phthalimide

HRID 379960

반응식

HRID 379960 반응식
C1([N:7]2[C:11](=[O:12])[C:10]3=[CH:13][CH:14]=[CH:15][CH:16]=[C:9]3[C:8]2=S)CCCCC1.SCCC[Si](OCC)(OCC)[O:23]CC>C(Cl)(Cl)Cl>[C:8]1(=[O:23])[NH:7][C:11](=[O:12])[C:10]2=[CH:13][CH:14]=[CH:15][CH:16]=[C:9]12

참가 물질

4

반응물 2

HCID 846581-Propanethiol, 3-(triethoxysilyl)-HCID 57083088HCID 57083088, 화합물

생성물 1

HCID 6809Phthalimide수율 119.6%

시약·촉매·용매 1

HCID 6212Chloroform용매2회

실험 절차

A 1-quart (0.946 l) glass reactor was charged with 400 ml of chloroform, 55.4 g (0.21 mole) of N-cyclohexylthiophthalimide, and 47.6 g (0.20 mole) of 3-mercaptopropyltriethoxysilane dissolved in 400 ml of chloroform. The reaction was stirred and allowed to stand overnight to give white needles of phthalimide (35.2 g) which were separated by filtration and identified by mass spectrometry analysis. The solvent was distilled from the filtrate to give 56.9 g of an oil identified as cyclohexyl-3-dithiopropyltriethoxysilane by mass spectrometry analysis. This oil (53 g) was dissolved in 100 ml of acetone and homogeneously dispersed into N330 carbon black, with the acetone being stripped away.

출처 및 근거

ORD 기록
ord-8780cb6fd2a247d2b562b9b86c32288f
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06300397B1

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