Acetic Anhydride → Tin(IV) acetate

반응식

[Sn].[C:2]([O-:5])(=[O:4])[CH3:3].[Sn+2:6].[C:7]([O-:10])(=[O:9])[CH3:8].[C:11]([O:14]C(=O)C)(=[O:13])[CH3:12]>>[C:2]([O-:5])(=[O:4])[CH3:3].[Sn+4:6].[C:7]([O-:10])(=[O:9])[CH3:8].[C:11]([O-:14])(=[O:13])[CH3:12].[C:2]([O-:5])(=[O:4])[CH3:3]

참가 물질

반응물 3

HCID 7918Acetic Anhydride

HCID 69488Stannous acetate

HCID 5352426Tin atom

생성물 1

HCID 9863446Tin(IV) acetate

실험 절차

Ruf, U.S. Pat. No. 5,068,373, Entitled Method for the Preparation of Anhydrous Tin—(IV)—Carboxylates, issued Nov. 26, 1991, relates to a method of reacting metallic tin or tin (II) acetate with an excess of acetic anhydride to produce tin (IV) acetate. The tin (IV) acetate is separated from the reaction mixture and used as separated or, if desired, is subsequently converted to tin (IV) carboxylate having four or more carbon atoms by reaction with the appropriate carboxylic acid.

출처 및 근거

ORD 기록: ord-47fda327a8d14b578f39aec7cb5397c8
출처 데이터셋: uspto-grants-2001_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06303808B1

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