Dimethyl Sulfide → Trimethylsulfonium methyl sulfate

HRID 392546

반응식

S([O-])(O)(=O)=O.[CH3:6][S+:7]([CH3:9])[CH3:8].[S:10]([O:15]C)([O:13][CH3:14])(=[O:12])=[O:11].CSC>>[CH3:14][O:13][S:10]([O-:15])(=[O:12])=[O:11].[CH3:6][S+:7]([CH3:9])[CH3:8]

참가 물질

반응물 3

HCID 1068Dimethyl Sulfide

HCID 6497Dimethyl Sulfate

HCID 10942955Sulfonium, trimethyl-, sulfate (1:1)

생성물 1

HCID 2760871Trimethylsulfonium methyl sulfate

반응 조건

온도: 0 °C

실험 절차

Synthesis of trimethysulfonium hydrogen sulfate: To dimethyl sulfate (10.0 mL, 1.05×10−1 mol) at 0° C. was added dimethyl sulfide (10.4 mL, 1.42×10−1 mol). After rapidly stirring at 0° C. for 30 minutes, the reaction was slowly warmed to room temperature yielding a crystalline solid, trimethylsulfonium methyl sulfate. After 3 hours, distilled water (20 mL) was added to form a clear solution of trimethylsulfonium sulfate.

후처리

temperaturethe reaction was slowly warmed to room temperature

출처 및 근거

ORD 기록: ord-a8941cee5f4f42d68566fd502884c095
출처 데이터셋: uspto-grants-2004_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06800766B2

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