tert-Butyl hydroperoxide → Cyclohexanol cyclohexanone

HRID 397370

반응식

HRID 397370 반응식
C(OO)(C)(C)C.S([O-])([O-])(=O)=O.[Na+].[Na+].[C:14]1(=[O:20])[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1>C(#N)C.C1CCCCC1>[C:14]1(=[O:20])[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1.[CH:14]1([OH:20])[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1

참가 물질

6

반응물 3

HCID 6410tert-Butyl hydroperoxideHCID 7967CyclohexanoneHCID 24436Sodium Sulfate

생성물 1

HCID 22492587Cyclohexanol cyclohexanone

시약·촉매·용매 2

HCID 6342Acetonitrile용매HCID 8078Cyclohexane용매2회

실험 절차

To an argon purged solution of Complex 3 (0.1 mM) in acetonitrile, cyclohexane (50 mM) was added followed by 20 mM of tert-butylhydroperoxide (t-BuOOH) (dissolved in di-t-butylether). The reaction mixture was maintained under an argon atmosphere for 30 min followed by the addition of an aqueous solution of sodium sulphate (0.4 M). The iron complex dissolved in the aqueous phase and the products (cyclohexane and cyclohexanone) were analysed by GC. Analyses yielded 0.5-1.5 mM of cyclohexanone +cyclohexanol (5-15 turnovers).

후처리

  1. temperatureThe reaction mixture was maintained under an argon atmosphere for 30 min
  2. dissolutionThe iron complex dissolved in the aqueous phase

출처 및 근거

ORD 기록
ord-47d52450d6ea4d3dacc379a5126d1475
출처 데이터셋
uspto-grants-2003_08
특허 번호
US06610641B2

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