3-Octyn-1-ol → 7-Octyn-1-ol

HRID 398219

반응식

HRID 398219 반응식
[CH2:1]([OH:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]#C.C(O)CC#CCCCC>NCCCN>[CH2:1]([OH:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[CH:8]

참가 물질

4

반응물 2

HCID 846943-Octyn-1-olHCID 38061428-Nonyn-1-ol

생성물 1

HCID 701007-Octyn-1-ol

시약·촉매·용매 1

HCID 4281,3-Propanediamine용매

실험 절차

The same procedure for 8-nonyn-1-ol was followed with 3-octyn-1-ol (6.89 g, 54.6 mmol), KH (6.57 g, 16.4 mmol), and 1,3-diaminopropane (60 mL). This produced 6.09 g of clear yellowish liquid (88%): IR (neat)ν 3360, 2896, 2116 cm−1; 1H—NMR δ 3.44 (t, 2H, J=6.6 Hz), 3.27 (bs, 1H), 2.04 (td, 2H, J=2.6 Hz, 6.6 Hz), 1.83 (t, 1H, J=2.6 Hz), 1.39 (m, 4H), 1.25 (m, 4H); 13C NMR δ 84.5, 68.3, 62.2, 32.3, 28.3, 25.2, (2C), 18.2; MS m/z 136.00 (m++Li). Anal. Calcd for C8H14O: C, 76.14; H, 11.18. Found: C, 76.04; H, 11.16.

출처 및 근거

ORD 기록
ord-e1f89fa5c3404f55b8c6a0a7b05fe2ed
출처 데이터셋
uspto-grants-2003_08
특허 번호
US06610835B1

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