{[4-(Methylsulfanyl)phenyl]methyl}(triphenyl)phosphanium chloride → HCID 12652959, 화합물

HRID 399079

반응식

HRID 399079 반응식
[Cl-].[CH3:2][S:3][C:4]1[CH:29]=[CH:28][C:7]([CH2:8][P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[CH:6][CH:5]=1>[Cl-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1>[CH3:2][S:3][C:4]1[CH:5]=[CH:6][C:7](/[CH:8]=[CH:8]/[C:7]2[CH:6]=[CH:5][C:4]([S:3][CH3:2])=[CH:29][CH:28]=2)=[CH:28][CH:29]=1

참가 물질

3

반응물 1

HCID 18969794{[4-(Methylsulfanyl)phenyl]methyl}(triphenyl)phosphanium chloride

생성물 1

HCID 12652959HCID 12652959, 화합물

시약·촉매·용매 1

HCID 70671Benzyltriphenylphosphonium chloride촉매

실험 절차

Following the procedure as describe in method 1, but sustituting 4-methylthiobenzyltriphenylphosphonium chloride for benzyltriphenylphosphonium chloride, the desired residue was purified by flash chromatography (silica gel; hexane/EtOAc (90:10)) and recrystallisation from hexane.

후처리

  1. customthe desired residue was purified by flash chromatography (silica gel; hexane/EtOAc (90:10)) and recrystallisation from hexane

출처 및 근거

ORD 기록
ord-92dd2f6185b44d6eb92558a7134d09c5
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05817700

연결된 노트

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