epsilon-CAPROLACTONE → epsilon-Caprolactone p-Dioxanone

HRID 399687

반응식

HRID 399687 반응식
[C:1]1(=[O:8])[O:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[O:9]1[CH2:14][CH2:13][O:12][CH2:11][C:10]1=[O:15]>>[C:1]1(=[O:8])[O:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[O:9]1[CH2:14][CH2:13][O:12][CH2:11][C:10]1=[O:15]

참가 물질

3

반응물 2

HCID 10401epsilon-CAPROLACTONEHCID 18233Dioxanone

생성물 1

HCID 86748302epsilon-Caprolactone p-Dioxanone

실험 절차

The procedure in Example 5A was substantially repeated, except that 68.48 grams (0.60 mole) of ε-caprolactone and 40.83 grams (0.40 mole) of p-dioxanone were used. The copolymer was dried under vacuum (0.1 mm Hg) at 80° C. for about 80 hours to remove any unreacted monomer. The copolymer had an inherent viscosity of 0.19 dL/g in HFIP at 25° C. The copolymer was a liquid at room temperature. The molar ratio of PCL/PDS was found to be 57.2/42.8 by proton NMR.

후처리

  1. customThe copolymer was dried under vacuum (0.1 mm Hg) at 80° C. for about 80 hours
  2. customto remove any unreacted monomer
  3. customat 25° C
  4. customat room temperature

출처 및 근거

ORD 기록
ord-e9a1dfb2969f449986c4c67f590dce31
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05824333

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