HCID 178468432, 화합물 → HCID 178470071, 화합물

HRID 400111노트

반응식

HRID 400111 반응식
[CH2:1]([O:3][C:4]([C:6]1[C:16]2[CH2:15][CH2:14][N:13]([CH2:17][C:18]3C=CC=CC=3)[CH2:12][CH2:11][C:10]=2[CH:9]=[N+:8]([O-])[C:7]=1[OH:25])=[O:5])[CH3:2]>C(O)C.[Ni]>[CH2:1]([O:3][C:4]([C:6]1[C:16]2[CH2:15][CH2:14][N:13]([CH2:17][CH3:18])[CH2:12][CH2:11][C:10]=2[CH:9]=[N:8][C:7]=1[OH:25])=[O:5])[CH3:2]

참가 물질

4

반응물 1

HCID 178468432HCID 178468432, 화합물

생성물 1

HCID 178470071HCID 178470071, 화합물

시약·촉매·용매 2

HCID 935Nickel촉매HCID 702Ethanol용매

실험 절차

Prepared from 4-ethoxycarbonyl-3-hydroxy-7-benzyl-6,7,8,9-tetrahydro-5H-pyrido[3,4-d]azepine 2-oxide by hydrogenation in ethanol at 130° C. in the presence of Raney nickel.

출처 및 근거

ORD 기록
ord-288df4fe5f8b4695a4333643bfd3f720
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05827849

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