Toluene → 2,3,5-Triiodobenzoic acid

반응식

[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].C1CCCCC1.C1(C)C=CC=CC=1>>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]

참가 물질

반응물 2

HCID 1140Toluene

HCID 131728537TIBA cyclohexane

생성물 1

HCID 69482,3,5-Triiodobenzoic acid

실험 절차

13.5 mL of TIBA/cyclohexane solution (113 g/L) were mixed with 3.2 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.92 g/mL, 15.3 mmol MAO) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 h at room temperature and transferred into a 50 mL Schlenk flask containing C-1 (28.4 mg, 38.3 μmol). The final solution was diluted with 7.7 mL of cyclohexane. Final mixture concentration=100 gTOT/L and 1.165 gmetallocene/L; color=dark red solution.

출처 및 근거

ORD 기록: ord-abb03a218be545a394e304edce7838d6
출처 데이터셋: uspto-grants-2014_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08742042B2

반응 노트

불러오는 중…