4-Methoxyphenol → 4-Methoxycyclohexanol (cis,trans)

HRID 406027

반응식

HRID 406027 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1.[H][H]>C(O)C>[CH3:1][O:2][CH:3]1[CH2:8][CH2:7][CH:6]([OH:9])[CH2:5][CH2:4]1

참가 물질

4

반응물 2

HCID 90154-MethoxyphenolHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 1403324-Methoxycyclohexanol (cis,trans)

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

4-Methoxyphenol (100 g) in ethanol (759 ml) was hydrogenated under 50 psi hydrogen using Nishimura catalyst (10.0 g) at rt for 4.5 h. The catalyst was filtered off; the solvent was removed in vacuo to yield the desired product as 95% pure yellowish liquid.

후처리

  1. customat rt
  2. customfor 4.5 h
  3. filtrationThe catalyst was filtered off
  4. customthe solvent was removed in vacuo

출처 및 근거

ORD 기록
ord-66c84cbcff4b405b833f38f35bbb2adf
출처 데이터셋
uspto-grants-2014_06
특허 번호
US08754079B2

연결된 노트

불러오는 중…