Formaldehyde → (1R,5R)-10-hydroxymethyl-2-pinene

반응식

[CH3:1][C:2]1([CH3:10])[CH:8]2[CH2:9][CH:3]1[CH2:4][CH2:5][C:6]2=[CH2:7].[CH2:11]=[O:12]>>[OH:12][CH2:11][CH2:7][C:6]1[C@@H:8]2[CH2:9][C@@H:3]([CH2:4][CH:5]=1)[C:2]2([CH3:10])[CH3:1]

참가 물질

반응물 2

HCID 712Formaldehyde

HCID 14896Beta-Pinene

생성물 1

HCID 6978972(1R,5R)-10-hydroxymethyl-2-pinene

실험 절차

A mixture of β-pinene (32 ml) and paraformaldehyde (4 g) in sealed tube was reacted for 18 hrs at 180° C. The reaction solution was distilled to give the title compound (15.5 g) having the following physical data:

후처리

customwas reacted for 18 hrs at 180° C
distillationThe reaction solution was distilled

출처 및 근거

ORD 기록: ord-e68a368eafa94ffeb9e2294b9496f4e5
출처 데이터셋: uspto-grants-1988_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04792550

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