Potassium Carbonate → N,N-diallyl-6-nitro-1,3-benzenediamine

HRID 428799

반응식

HRID 428799 반응식
F[C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][C:8]=1[N+:9]([O-:11])=[O:10])[NH2:5].CN1CCCC1=O.[CH2:19]([NH:22][CH2:23][CH:24]=[CH2:25])[CH:20]=[CH2:21].C(=O)([O-])[O-].[K+].[K+]>O>[CH2:19]([N:22]([CH2:23][CH:24]=[CH2:25])[C:2]1[C:8]([N+:9]([O-:11])=[O:10])=[CH:7][CH:6]=[C:4]([NH2:5])[CH:3]=1)[CH:20]=[CH2:21]

참가 물질

6

반응물 4

HCID 11430Potassium CarbonateHCID 13387N-methyl-2-pyrrolidoneHCID 31279DiallylamineHCID 754013-Fluoro-4-nitroaniline

생성물 1

HCID 22251449N,N-diallyl-6-nitro-1,3-benzenediamine수율 98.6%

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
120 °C

실험 절차

A mixture of 3-fluoro-4-nitroaniline (1.56 g, 10 mmol), 1-methylpyrolidinone (10 mL), diallylamine (1.94 g, 20 mmol) and potassium carbonate (1.38 g, 10 mmol) was heated to 115-125 ° C. for 9.5 h. The mixture was diluted with water, and extracted with ethyl ether. The combined extracts were washed with water, washed with saturated brine solution, and dried over magnesium sulfate. The extract was concentrated to give N,N-diallyl-6-nitro-1,3-benzenediamine as an orange oil (2.3 g).

후처리

  1. extractionextracted with ethyl ether
  2. washThe combined extracts were washed with water
  3. washwashed with saturated brine solution
  4. dry with materialdried over magnesium sulfate
  5. concentrationThe extract was concentrated

출처 및 근거

ORD 기록
ord-28b93eaa005f48068dd8c1543a6e8d6e
출처 데이터셋
uspto-grants-2001_11
특허 번호
US06313348B1

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