Azobisisobutyronitrile → Maleic anhydride t-butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate 3-hydroxypropyl 5-norbornene-2-carboxylate

HRID 429011노트

반응식

HRID 429011 반응식
[C:1]1(=[O:7])[O:6][C:4](=[O:5])[CH:3]=[CH:2]1.[CH:8]12[CH2:15][CH2:14][CH:11]([CH:12]=[CH:13]1)[CH2:10][CH:9]2[C:16]([O:18][C:19]([CH3:22])([CH3:21])[CH3:20])=[O:17].N(C(C)(C)C#N)=NC(C)(C)C#N>O1CCCC1>[C:4]1(=[O:5])[O:6][C:1](=[O:7])[CH:2]=[CH:3]1.[CH:8]12[CH2:15][CH2:14][CH:11]([CH:12]=[CH:13]1)[CH2:10][CH:9]2[C:16]([O:18][C:19]([CH3:22])([CH3:21])[CH3:20])=[O:17].[CH:8]12[CH2:13][CH:11]([CH:14]=[CH:15]1)[CH2:10][CH:9]2[C:16]([O:18][CH2:19][CH2:22][CH2:4][OH:5])=[O:17]

참가 물질

5

반응물 3

HCID 6547AzobisisobutyronitrileHCID 7923Maleic AnhydrideHCID 18413667t-Butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate

생성물 1

HCID 86757578Maleic anhydride t-butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate 3-hydroxypropyl 5-norbornene-2-carboxylate수율 50%

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

Maleic anhydride (1 mol.), t-butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate (0.5 mol.), and 3-hydroxy propyl 5-norbornene-2-carboxylate (0.5 mol.) were dissolved in 200 gms of tetrahydrofuran (THF), 6 gms of 2,2′-azobisisobutyronitrile (AIBN) was added thereto, and then the resultant solution was reacted at a temperature of 67° C. in a nitrogen atmosphere for 10 hours. After a high molecule weight was achieved by the reaction, the resultant product was precipitated in an ethyl ether solvent. The gathered precipitate was dried, and 150 gms of the desirable poly(maleic anhydride/t-butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate/3-hydroxypropyl 5-norbornene-2-carboxylate) polymer was obtained at a yield of about 50%. NMR spectra of the polymer is illustrated in FIG. 5.

후처리

  1. customAfter a high molecule weight was achieved by the reaction
  2. customthe resultant product was precipitated in an ethyl ether solvent
  3. customThe gathered precipitate was dried

출처 및 근거

ORD 기록
ord-cf7fa89251d3477eb64d7e31765bd6fd
출처 데이터셋
uspto-grants-2001_11
특허 번호
US06316162B1

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