Styrene → p-Tert-butoxystyrene styrene

HRID 430913

반응식

HRID 430913 반응식
[C:1]([O:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1)([CH3:4])([CH3:3])[CH3:2].[CH2:14]=[CH:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[C:1]([O:5][C:6]1[CH:7]=[CH:8][C:9]([CH:10]=[CH2:11])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3].[CH2:14]=[CH:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

참가 물질

3

반응물 2

HCID 7501StyreneHCID 5775311-(Tert-butoxy)-4-ethenylbenzene

생성물 1

HCID 69102216p-Tert-butoxystyrene styrene

실험 절차

The same reaction and after-treatment using 81.1 g (0.46 mole) of p-tert-butoxystyrene and 4.6 g (0.04 mole) of styrene as described in Production Example 4-(1) were conducted to give 80.5 g of poly(p-tert-butoxystyrene/styrene) as white powders. Then, the polymer was subjected to the same reaction and after-treatment as described in Production Example 9-(1) to give 44.0 g of poly(p-hydroxystyrene/styrene) as white powders. A ratio of p-hydroxystyrene unit and styrene unit was about 92:8 by 1HNMR. Mw: about 15500, Mw/Mn: 1.08 (GPC method: polystyrene as standard).

후처리

  1. customThe same reaction

출처 및 근거

ORD 기록
ord-12e6d8d90c484058b50236fc8c75e009
출처 데이터셋
uspto-grants-2003_12
특허 번호
US06656660B1

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