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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 431153생성일: 2026년 10월 27일

1-Ethynyl-4-fluorobenzene → Z-4-fluorostyryl 2-chlorobenzylsulfide

https://huagongshe.com/reaction/431153

반응식

참여 물질

역할이름HCID투입량
반응물1-Ethynyl-4-fluorobenzeneHCID 522627—
반응물2-Chlorobenzyl mercaptanHCID 580759—
반응물SodiumHCID 5360545—
생성물Z-4-fluorostyryl 2-chlorobenzylsulfideHCID 86588942—

반응 단계

A solution of 4-fluorophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-fluorostyryl 2-chlorobenzylsulfide. The title compound was obtained in 74% yield following oxidation. 1HNMR (CDC13) δ4.55 (2H, s), 6.66 (1H, d, JH,H=11.94), 7.20-7.65 (8H aromatic+1H ethylenic).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06656973B2
출처 데이터셋uspto-grants-2003_12
ORD IDord-d57330e792bf444080d3a26cba83ac7b
출처 메모uspto-grants-2003_12