HRID431153

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID522627

1-Ethynyl-4-fluorobenzene

C8H5F

HCID580759

2-Chlorobenzenemethanethiol

C7H7ClS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Fc1ccc(/C=C\C(SC(/C=C\c2ccc(F)cc2)c2ccccc2Cl)c2ccccc2Cl)cc1$

HCID86588942

未命名化合物

PROCEDURE

实验过程

A solution of 4-fluorophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-fluorostyryl 2-chlorobenzylsulfide. The title compound was obtained in 74% yield following oxidation. 1HNMR (CDC13) δ4.55 (2H, s), 6.66 (1H, d, JH,H=11.94), 7.20-7.65 (8H aromatic+1H ethylenic).