Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Chromic Acid → 4-Cyclopentene-1,3-diol, 1-acetate, (1R,3S)-rel-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Chromic Acid | HCID 24425 | — |
| 반응물 | 4-Oxocyclopent-2-en-1-yl acetate | HCID 343117 | — |
| 반응물 | (1S,4S)-4-hydroxycyclopent-2-en-1-yl acetate | HCID 12773776 | — |
| 생성물 | 4-Cyclopentene-1,3-diol, 1-acetate, (1R,3S)-rel- | HCID 9855498 | — |
반응 단계
The trans-3-acetoxy-5-hydroxycyclopent-1-ene obtained by using baker's yeast and whose absolute configuration was determined to be of R-configuration was converted to 4-acetoxycyclopent-2-en-1-one by oxidation with chromic acid. When the specific rotation of this compound was found to be +74°.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04008125 |
| 출처 데이터셋 | uspto-grants-1977_02 |
| ORD ID | ord-616c92a305f34e4c8fe816b4522a6aaf |
| 출처 메모 | uspto-grants-1977_02 |