Benzene → tert-Butyl 3,4-dinitrobenzoate

HRID 436265노트

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HRID 436265 반응식
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]=1[N+:13]([O-:15])=[O:14])[C:7](Cl)=[O:8])([O-:3])=[O:2].C1C=CC=CC=1.N1C=CC=CC=1.[C:28]([OH:32])([CH3:31])([CH3:30])[CH3:29]>>[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]=1[N+:13]([O-:15])=[O:14])[C:7]([O:32][C:28]([CH3:31])([CH3:30])[CH3:29])=[O:8])([O-:3])=[O:2]

참가 물질

5

반응물 4

HCID 241BenzeneHCID 1049PyridineHCID 6386tert-ButanolHCID 118064913,4-dinitrobenzoyl Chloride

생성물 1

HCID 20551560tert-Butyl 3,4-dinitrobenzoate수율 49%

실험 절차

The crude 3,4-dinitrobenzoyl chloride, 500 ml. of benzene, 25 ml. of pyridine and 22 g. (0.30 of t-butyl alcohol were reacted as in Example 6 (A), second paragraph, to provide 33 g. (49 percent yield) of t-butyl 3,4-dinitrobenzoate.

후처리

  1. customto provide 33 g

출처 및 근거

ORD 기록
ord-43dd447432ff4159b15c8b38689f51d2
출처 데이터셋
uspto-grants-1977_02
특허 번호
US04008243

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