Citrulline → N-(2,3,4,5-tetrahydroxy-pentyl)-L-(+)-citrulline
반응식
O=[CH:2][C@@H:3]([C@@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[NH2:11][C@H:12]([C:20]([OH:22])=[O:21])[CH2:13][CH2:14][CH2:15][NH:16][C:17]([NH2:19])=[O:18]>[Ni]>[OH:4][CH:3]([CH:5]([OH:6])[CH:7]([OH:8])[CH2:9][OH:10])[CH2:2][NH:11][C@H:12]([C:20]([OH:22])=[O:21])[CH2:13][CH2:14][CH2:15][NH:16][C:17]([NH2:19])=[O:18]참가 물질
4
실험 절차
The product was made from D-ribose and L-(+)-citrulline using Raney nickel as a catalyst and heating for 2 hours to 50° C. and for 4 hours to 70° C. The product obtained had a melting point of 172° to 175° C. (decomposition) and an RF -value of 0.52 (determined as indicated under Example T).
후처리
- temperatureheating for 2 hours to 50° C. and for 4 hours to 70° C
- customThe product obtained
출처 및 근거
- ORD 기록
- ord-83b4416ca09743c682d22a1ff915884c
- 출처 데이터셋
- uspto-grants-1977_06
- 특허 번호
- US04032676
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