Hydrochloric Acid → (6-Chloro-2-oxohexyl) triphenylphosphonium chloride

HRID 441603

반응식

HRID 441603 반응식
[Cl-:1].[O:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C:3]1=[CH:8][P+:9]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.Cl>>[Cl-:1].[Cl:1][CH2:7][CH2:6][CH2:5][CH2:4][C:3](=[O:2])[CH2:8][P+:9]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

참가 물질

3

반응물 2

HCID 313Hydrochloric AcidHCID 73680070[(tetrahydro-2H-pyran-2-ylidene)methyl]triphenylphosphonium chloride

생성물 1

HCID 20526427(6-Chloro-2-oxohexyl) triphenylphosphonium chloride

실험 절차

A solution consisting of 18.5 parts of [(tetrahydro-2H-pyran-2-ylidene)methyl]triphenylphosphonium chloride in 100 parts by volume of concentrated hydrochloric acid is heated at the reflux temperature for about 36 hours, then is cooled to room temperature. The solvent is removed by distillation under reduced pressure to afford (6-chloro-2-oxohexyl)triphenyl-phosphonium chloride, identical with the product of Example 2.

후처리

  1. temperatureis heated at the reflux temperature for about 36 hours
  2. customThe solvent is removed by distillation under reduced pressure

출처 및 근거

ORD 기록
ord-031a4fa3dbd347f598fe8324b6ccb3c9
출처 데이터셋
uspto-grants-1977_08
특허 번호
US04041050

연결된 노트

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