Lithium Hydroxide → HCID 12912741, 화합물
반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7](Cl)=[CH:6][N:5]=1)([O-:3])=[O:2].[Cl:11][C:12]1[CH:17]=[CH:16][C:15]([SH:18])=[CH:14][CH:13]=1.[OH-].[Li+].CN(C=O)C>O>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:18][C:15]2[CH:16]=[CH:17][C:12]([Cl:11])=[CH:13][CH:14]=2)=[CH:6][N:5]=1)([O-:3])=[O:2]참가 물질
6
실험 절차
2-Nitro-5-chloropyridine (9.5 grams), 4-chlorothiophenol (8.7 grams), and lithium hydroxide (4 grams) were mixed in 100 ml. of DMF and the reaction mixture was stirred overnight (about 18 hours) at room temperature. The reaction mixture was then poured into water and the product separated by filtration and crystallized from ethanol-hexanes, yield, 10.0 grams, m.p., 96°-98° C.
후처리
- customthe product separated by filtration
- customcrystallized from ethanol-hexanes
- customyield
- customm.p., 96°-98° C.
출처 및 근거
- ORD 기록
- ord-59219e31105d4d478d72800c39063248
- 출처 데이터셋
- uspto-grants-1981_04
- 특허 번호
- US04264605
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