1,12-Dodecanediamine → N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine
반응식
[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][NH2:14].[CH3:15][NH:16][C:17](SC)=[CH:18][N+:19]([O-:21])=[O:20]>O>[CH3:15][NH:16][C:17]([NH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][NH2:14])=[CH:18][N+:19]([O-:21])=[O:20]참가 물질
4
실험 절차
A mixture of 1,12-diaminododecane (3 g) and N-methyl-1-(methylthio)-2-nitroethenamine (1.48 g) in water (50 ml) was stirred at room temperature for 20 hours. The solution was evaporated in vacuo and the residue chomatographed (silica/methanol). The appropriate eluate was evaporated to yield the title compound (1.8 g), mp. 123°-125°.
후처리
- customThe solution was evaporated in vacuo
- customThe appropriate eluate was evaporated
출처 및 근거
- ORD 기록
- ord-224401e7109b4bb1a375c4eae73c93cf
- 출처 데이터셋
- uspto-grants-1981_04
- 특허 번호
- US04264614
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