5-Bromo-2-chloronitrobenzene → 2-Chloro-5-bromoaniline

HRID 461206노트

반응식

HRID 461206 반응식
[Br:1][C:2]1[CH:3]=[CH:4][C:5]([Cl:11])=[C:6]([N+:8]([O-])=O)[CH:7]=1.[H][H]>CO.[Ni]>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([Cl:11])=[C:6]([CH:7]=1)[NH2:8]

참가 물질

5

반응물 2

HCID 8179745-Bromo-2-chloronitrobenzeneHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 38307312-Chloro-5-bromoaniline

시약·촉매·용매 2

HCID 935Nickel촉매HCID 887Methanol용매

실험 절차

90 g of 5-bromo-2-chloronitrobenzene were hydrogenated in 500 ml of methanol at room temperature and under normal pressure with Raney-Nickel as catalyst and hydrogen. Colorless crystals, melting point: 47° C.

출처 및 근거

ORD 기록
ord-5dec04d979244d97a4d35c7d8daaa9e1
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04061761

반응 노트

불러오는 중…