Benzoyl Peroxide → HCID 86735267, 화합물

HRID 461412노트

반응식

HRID 461412 반응식
C1C(C(OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH2:29]([CH2:32][CH2:33][CH2:34][C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)[CH:30]=[CH2:31]>C(Cl)(Cl)Cl>[CH2:29]([CH:32]=[CH:33][CH2:34][C:35]1[CH:36]=[CH:37][CH:38]2[O:8][CH:39]2[CH:40]=1)[CH2:30][CH3:31]

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 519188hex-5-enylbenzeneHCID 523077Perbenzoic acid

생성물 1

HCID 86735267HCID 86735267, 화합물수율 76%

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

To perbenzoic acid in chloroform prepared from 65.5 g of benzoylperoxide was added 1.45 g of p-allylpropylbenzene and the mixture was allowed to stand at 5° C for 6 days. After the completion of the reaction, the mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was distilled under reduced pressure to give 12.1 g (yield 76%) of p-n-propylallylbenzene oxide as colourless liquid.

후처리

  1. customAfter the completion of the reaction
  2. washthe mixture was washed with 2% sodium hydroxide solution, water, Mohr's salt solution
  3. dry with materialwater, and dried over anhydrous sodium sulfate
  4. customThe solvent was evaporated
  5. customto obtain the residue, which
  6. distillationwas distilled under reduced pressure

출처 및 근거

ORD 기록
ord-5a7c4a84a60c48728305ae320bc3d928
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04062862

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