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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Benzoyl Peroxide → HCID 86735274, 화합물

HRID 461420
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HRID 461420 반응식
C1C(C(OO)=[O:8])=CC=CC=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH2:29]([CH:36]=[CH:37][CH2:38][C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)[C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1>C(Cl)(Cl)Cl>[CH2:38]([CH:37]=[CH:36][CH2:29][C:30]12[O:8][CH:31]1[CH:32]=[CH:33][CH:34]=[CH:35]2)[C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 518795o-BenzylallylbenzeneHCID 523077Perbenzoic acid

생성물 1

HCID 86735274HCID 86735274, 화합물

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

To perbenzoic acid in chloroform prepared from 15 g of benzoylperoxide was added 6.0 g of o-benzylallylbenzene and the mixture was allowed to stand at 5° C for 3 days. The mixture was washed with 2% sodium hydroxide solution, Mohr's salt solution, then water, and dried over anhydrous sodium sulfate. The solvent was evaporated to obtain the residue, which was chromatographed over a silica gel, and as eluted with benzene/n-hexane (1/1), there was obtained 1.5 g of o-benzylallylbenzene oxide as an oily substance.

후처리

  1. washThe mixture was washed with 2% sodium hydroxide solution, Mohr's salt solution
  2. dry with materialwater, and dried over anhydrous sodium sulfate
  3. customThe solvent was evaporated
  4. customto obtain the residue, which
  5. customwas chromatographed over a silica gel
  6. washas eluted with benzene/n-hexane (1/1)

출처 및 근거

ORD 기록
ord-e99f2065959448b79f610e3bd78a3ce1
출처 데이터셋
uspto-grants-1977_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04062862

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