Benzoyl Peroxide → Methyl 2-(1-bromoethyl)benzoate
반응식
[CH2:1]([C:3]1[CH:12]=[CH:11][CH:10]=[CH:9][C:4]=1[C:5]([O:7][CH3:8])=[O:6])[CH3:2].[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:13][CH:1]([C:3]1[CH:12]=[CH:11][CH:10]=[CH:9][C:4]=1[C:5]([O:7][CH3:8])=[O:6])[CH3:2]참가 물질
5
실험 절차
A mixture of 10.7 g. (0.065 mole) of methyl 2-ethylbenzoate, 12.5 g. (0.07 mole) of N-bromosuccinimide, 50 mg. of benzoyl peroxide, and 125 ml. of carbon tetrachloride is stirred at reflux until the reaction is complete in 2 hours. The precipitated succinimide is filtered from the cooled mixture and the filtrate is evaporated to dryness under reduced pressure leaving methyl 2-(1-bromoethyl)benzoate as the residual yellow oil in quantitative yield.
후처리
- additionA mixture of 10.7 g
- temperatureat reflux until the reaction
- filtrationThe precipitated succinimide is filtered from the cooled mixture
- customthe filtrate is evaporated to dryness under reduced pressure
출처 및 근거
- ORD 기록
- ord-9f80e3ccfa154d83ac3dbd8a07af416a
- 출처 데이터셋
- uspto-grants-1977_12
- 특허 번호
- US04064139
반응 노트
불러오는 중…