Carbon Disulfide → HCID 178527929, 화합물

HRID 461847

반응식

HRID 461847 반응식
[NH:1]([C:3]1[S:4][C:5]2[CH:11]=[CH:10][CH:9]=[CH:8][C:6]=2[N:7]=1)[NH2:2].[OH-].[K+].[C:14](=S)=[S:15]>C(O)C>[N:1]1[N:2]=[C:14]([SH:15])[N:7]2[C:6]3[CH:8]=[CH:9][CH:10]=[CH:11][C:5]=3[S:4][C:3]=12

참가 물질

5

반응물 3

HCID 6348Carbon DisulfideHCID 119882-Benzothiazolinone, hydrazoneHCID 14797Potassium Hydroxide

생성물 1

HCID 178527929HCID 178527929, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

2-Hydrazinobenzothiazole (300 grams), potassium hydroxide (100 grams), and 225 milliliters of carbon disulfide were refluxed for 60 hours in 5500 milliliters of ethanol. A light yellow solid began precipitating out shortly after the beginning of reflux. The solid was collected by filtration and dissolved in water to which 1500 milliliters of 0.5N hydrochloric acid were added. The mixture thickened; the desired s-triazolo(3,4-b)benzothiazole-3-thiol product was collected by filtration, m.p., 242° C.

후처리

  1. customA light yellow solid began precipitating out shortly after the beginning
  2. temperatureof reflux
  3. filtrationThe solid was collected by filtration
  4. dissolutiondissolved in water to which 1500 milliliters of 0.5N hydrochloric acid
  5. additionwere added
  6. filtrationthe desired s-triazolo(3,4-b)benzothiazole-3-thiol product was collected by filtration, m.p., 242° C.

출처 및 근거

ORD 기록
ord-98c5a795e4cf409c8b4c26428f017b20
출처 데이터셋
uspto-grants-1977_12
특허 번호
US04064261

연결된 노트

불러오는 중…