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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Methacrylic Acid → Hydroxyacetone acrylate methyl methacrylate methacrylic acid

HRID 464438
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HRID 464438 반응식
CCCCC(C[O:9][C:10]([CH2:12][CH:13](S([O-])(=O)=O)C(OCC(CCCC)CC)=O)=[O:11])CC.[Na+].C(O)(=O)C=C.[OH:35][CH2:36][C:37](=[O:39])[CH3:38].[C:40]([O:45][CH3:46])(=[O:44])[C:41]([CH3:43])=[CH2:42].[C:47]([OH:52])(=[O:51])[C:48]([CH3:50])=[CH2:49].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+]>O>[C:10]([OH:11])(=[O:9])[CH:12]=[CH2:13].[OH:35][CH2:36][C:37](=[O:39])[CH3:38].[C:40]([O:45][CH3:46])(=[O:44])[C:41]([CH3:43])=[CH2:42].[C:47]([OH:52])(=[O:51])[C:48]([CH3:50])=[CH2:49]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

7

반응물 5

HCID 4093Methacrylic AcidHCID 6658Methyl MethacrylateHCID 62648Ammonium PersulfateHCID 23673837Docusate SodiumHCID 86740374Hydroxyacetone acrylate

생성물 1

HCID 86740373Hydroxyacetone acrylate methyl methacrylate methacrylic acid

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
80 °C

실험 절차

A mixture of 128 grams of deionized water and 0.20 gram of emulsifier (dioctyl sodium sulfosuccinate, available as Aerosol OT-75 from American Cyanamid Company) was heated to 80° C. under a nitrogen atmosphere. To this mixture was added a first portion (five parts by weight of the total) of a monomeric mixture consisting of 25 grams hydroxyacetone acrylate prepared as described in EXAMPLE 1, 36.2 grams methyl methacrylate, 1.25 grams methacrylic acid and 0.12 gram of Aerosol OT-100 emulsifier. After five minutes, 0.25 gram of ammonium peroxydisulfate was introduced into the resulting mixture. Subsequently, after a one-minute delay, there was commenced the gradual addition of the remaining portion of the aforedescribed mixture (the remaining 95 parts). The addition of this remaining portion was completed in three hours and, thereafter, the reaction contents were maintained at 80° C. for one hour. A latex (yield of 180 grams) having a solids content of 30% by weight was obtained.

후처리

  1. additionTo this mixture was added a first portion (five parts by weight of the total) of a monomeric mixture
  2. customprepared
  3. additionthe gradual addition of the remaining portion of the aforedescribed mixture (the remaining 95 parts)
  4. additionThe addition of this remaining portion
  5. waitwas completed in three hours
  6. customthe reaction contents
  7. temperaturewere maintained at 80° C. for one hour
  8. customwas obtained

출처 및 근거

ORD 기록
ord-d7b2fdd971434359a7b3590dcc4dd804
출처 데이터셋
uspto-grants-1985_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04547451

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