Methyltrimethoxysilane → Octadecylamine

HRID 465297

반응식

HRID 465297 반응식
C[Si](OC)(OC)OC.[C:9]1([CH3:15])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[N:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[CH2:21]([NH2:16])[CH2:20][CH2:19][CH2:18][CH2:17][CH2:13][CH2:14][CH2:9][CH2:10][CH2:11][CH2:12][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:9][CH3:15]

참가 물질

3

반응물 2

HCID 14456MethyltrimethoxysilaneHCID 22007288Pyridine toluene

생성물 1

HCID 15793Octadecylamine

실험 절차

Fractogel phosphate (1; 5 g) containing a trace amount of pyridine was slurried with octadecylamine (6 g) and left at 60° C. for 2 days. Toluene (100 ml) was added to the flask and the mixture refluxed for 24 hours. The mixture was then filtered and the gel washed with methanol to yield Fractogel C-18 (4). The resin was capped with methyltrimethoxy silane in toluene-pyridine at 60° C. for 24 hours. Analysis showed; C, 48.82; H, 6.26; N, 5 1.34%.

출처 및 근거

ORD 기록
ord-11db8ccf89ef4a3ab2606aaebba153a3
출처 데이터셋
uspto-grants-1992_10
특허 번호
US05153166

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