1-Octene → Gamma-Decalactone

HRID 46741

반응식

HRID 46741 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

참가 물질

4

반응물 2

HCID 81251-OcteneHCID 517044Potassium Acetate

생성물 1

HCID 12813Gamma-Decalactone수율 31%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Octene-1 in an amount of 2.2 grams and 23.6 grams of ceric acetate were refluxed under nitrogen in 200 milliliters of glacial acetic acid containing 60 grams of potassium acetate for less than 0.4 hour, there being obtained a 31% yield of gamma-n-hexyl butyrolactone.

출처 및 근거

ORD 기록
ord-b1b112f817fe40b399d7745d85d5634b
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04175089

연결된 노트

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