1-Octene → Gamma-Decalactone

HRID 46744

반응식

HRID 46744 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

참가 물질

4

반응물 2

HCID 81251-OcteneHCID 517044Potassium Acetate

생성물 1

HCID 12813Gamma-Decalactone수율 74%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Octene-1 in an amount of 3.37 g. and 4.8 g. of freshly prepared MnO2.4H2O were mixed with and heated under nitrogen in 300 ml. glacial acetic acid containing 90 g. potassium acetate. After a reaction time of less than two hours, gamma-n-hexyl-butyrolactone was obtained in 74% yield.

후처리

  1. temperatureheated under nitrogen in 300 ml

출처 및 근거

ORD 기록
ord-3c2d463041064f17a5965d17a1397be7
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04175089

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