1-Octene → Gamma-Decalactone

HRID 46746

반응식

HRID 46746 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

참가 물질

4

반응물 2

HCID 81251-OcteneHCID 517044Potassium Acetate

생성물 1

HCID 12813Gamma-Decalactone수율 48%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Octene-1 in an amount of 2.2 g. and 23.6 g. of ceric ammonium nitrate, Ce(NH4)2 (NO3)6, were refluxed under nitrogen in 200 ml. glacial acetic acid containing 60 g. potassium acetate for less than 0.5 hour, there being obtained a 48% yield of gamma-n-hexyl-butyrolactone.

출처 및 근거

ORD 기록
ord-2c03d4a37bfe48c9975a949c07039ab8
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04175089

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